Li-rich anti-perovskite Li3OCl films with enhanced ionic conductivity.
نویسندگان
چکیده
Anti-perovskite solid electrolyte films were prepared by pulsed laser deposition, and their room-temperature ionic conductivity can be improved by more than an order of magnitude in comparison with its bulk counterpart. The cyclability of Li3OCl films in contact with lithium was evaluated using a Li/Li3OCl/Li symmetric cell, showing self-stabilization during cycling test.
منابع مشابه
Antiperovskite Li3OCl Superionic Conductor Films for Solid‐State Li‐Ion Batteries
Antiperovskite Li3OCl superionic conductor films are prepared via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10-4 S cm-1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. The applicability of Li3OCl as a solid electrolyte for Li-ion batteries is demonstrated.
متن کاملDefect chemistry and lithium transport in Li3OCl anti-perovskite superionic conductors.
Lithium-rich anti-perovskites (LiRAPs) are a promising family of solid electrolytes, which exhibit ionic conductivities above 10(-3) S cm(-1) at room temperature, among the highest reported values to date. In this work, we investigate the defect chemistry and the associated lithium transport in Li3OCl, a prototypical LiRAP, using ab initio density functional theory (DFT) calculations and classi...
متن کاملEffect of oxygen pressure on structure and ionic conductivity of epitaxial Li0.33La0.55TiO3 solid electrolyte thin films produced by pulsed laser deposition
We report on the ionic conductivity of Li0.33La0.55TiO3 (LLTO) epitaxial films grown on the (100) and (111) surfaces of single crystal SrTiO3 (STO) substrates at different oxygen partial pressures (from 1.33 to 26.66 Pa). The films are intended for use as solid electrolytes for all-solid-state Li-ion batteries, and the epitaxial growth for modeling the electrolyte single crystal properties. The...
متن کاملVacancies Job in Oxide Perovskite Thin Films
Point defects can affect considerably the structural, magnetic, and transport properties of perovskite-structure materials with chemical formula ABO3. Oxygen vacancies (VO), for example, enable ionic conductivity in perovskite-based solid solutions to be used for electrochemical applications such as solid oxide fuel and electrolysis cells [1]. Likewise, VO can distort significantly the equilibr...
متن کاملStructural origin of the enhanced ionic conductivity upon Nb doping in Sr11Mo4O23 defective double perovskite.
We report a substantial enhancement of the oxide-ion conductivity in Sr11Mo4O23 achieved by Nb doping the Mo sites. This series responds to the formula: Sr11Mo4-xNbxO23-δ (with x = 0.0, 0.5 and 1.0). The original structure can be related to the conventional double perovskite; however, it presents a broken corner sharing connectivity of the octahedral framework, hence leading to a complex and hi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Chemical communications
دوره 50 78 شماره
صفحات -
تاریخ انتشار 2014